Answers revealed in the comments.
Game 1
Name both European countries whose most populous cities begin with the letter “Z.”
Game 2
In addition to Twilight Sparkle, there are six main characters who have appeared in over half of the 222 episodes of My Little Pony: Friendship is Magic. Name any one of those six characters.
hebspeaks 
Game one answers:
Switzerland
Croatia
Game 2 answers:
Applejack
Rarity
Fluttershy
Rainbow Dash
Pinkie Pie
Spike